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:: Volume 13, Issue 3 (12-2020) ::
2020, 13(3): 71-82 Back to browse issues page
TiO2 Encapsulated into Zeolitic Imidazolate Framework (TiO2@ZIF-8) as an Efficient Nanophotocatalyst for Degradation of Paraquat Herbicide
Fariba Dashtestani , Vahid Mohagheghi , Leila Ma'mani * , Kobra Maafi
Department of Nanotechnology, Agricultural Biotechnology Research Institute of Iran (ABRII), Agricultural Research Education and Extension Organization (AREEO), Karaj, Iran
Abstract:   (2450 Views)
In this research, preparation, characterization, and evaluation of TiO2 encapsulated into zeolitic imidazolate framework (TiO2@ZIF-8) nanophotocatalyst was investigated as an efficient photo-degradation of paraquat (PQ) herbicide from aqueous samples. This study was performed using a ZIF-8-based nanophotocatalyst and a reactor consisting of an ultraviolet (UV) source and a reaction chamber. The effects of various parameters including contaminant concentration, amount of nanophotocatalyst, and pH reaction time were investigated on the removal efficiency of contaminant by the TiO2@ZIF-8 nanophotocatalyst. The results showed by increasing the amount of the TiO2@ZIF-8 nanophotocatalyst and pH, the removal of paraquat showed an increase. The optimal condition was found as nanophotocatalyst concentration (0.05 g.L-1), pH (7) at room temperature for 15 min for removal of 99.8% paraquat. According to the results, TiO2@ZIF-8 emerged as an efficient, robust, and recyclable nanophotocatalyst, which is a potential and environmentally friendly process for the removal of toxic chemical herbicide as hazardous organic contaminants from aqueous samples. The facile fabrication approach and the enhanced photocatalytic activity of TiO2@ZIF-8 were highlighted and notably showed good reusability in 8 consecutive cycles.
Keywords: TiO2, Zeolitic Imidazolate Framework, Photocatalyst, Paraquat.
Full-Text [PDF 1213 kb]   (1357 Downloads)    
Type of Study: Research | Subject: Special
Received: 2021/05/30 | Accepted: 2021/06/15 | Published: 2020/12/19
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Dashtestani F, Mohagheghi V, Ma'mani L, Maafi K. TiO2 Encapsulated into Zeolitic Imidazolate Framework (TiO2@ZIF-8) as an Efficient Nanophotocatalyst for Degradation of Paraquat Herbicide. Journal of Biosafety 2020; 13 (3) :71-82
URL: http://journalofbiosafety.ir/article-1-408-en.html


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Creative Commons License This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Volume 13, Issue 3 (12-2020) Back to browse issues page
فصل نامه علمی ایمنی زیستی Journal of Biosafety
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