|
Investigation of Adsorption of Sulfur Chemicals agents Simulants Using Polyacrylonitrile and Polyoxomolybdate Nanofibers
|
Reza Haddad *   |
| Assistant Professor of Inorganic Chemistry, Department of Police Equipment and Technologies, Policing Sciences and Social Studies Institute, Tehran, Iran. |
|
|
Abstract: (1705 Views) |
In the present study, composite nanofibers PAN NFs/[Mo132] was prepared using polyacrylonitrile and supramolecular nanostructure [Mo132] under electrospinning process. The aim of this study was to investigate the adsorption of blister-like chemical agents such as 2-chloroethyl ethyl sulfide and 2-chloroethyl phenyl sulfide in the presence of these nanofibers. The structure of nanofibers, surface morphology, and other properties were characterized by SEM, TEM, FT-IR and UV-Vis methods. The average diameter of nanofibers using SEM images was about 80 nm. PAN/[Mo132] nanofibers showed an adsorption efficiency of about 92-94% after about 4 hours. The progress of the reaction was examined by gas chromatography. The results showed that the rate and amount of the adsorption of 2-CEES and 2-CEPS increased with increasing the amount of [Mo132], which indicates the effect and role of this nanocluster in the performance of nanofibers. In this study, the effect of factors such as amount PAN/[Mo132], time, temperature and solvent on the rate of adsorption process was investigated.
|
|
| Keywords: Electrospinning, Polyacrylonitrile, Terrorist Attacks, Supramolecular, Blistering Chemical Agents |
|
|
Full-Text [PDF 1380 kb]
(307 Downloads)
|
Type of Study: Research |
Subject:
Special
Received: 2021/10/17 | Accepted: 2022/03/1 | Published: 2022/03/1
|
|
|
|
|
|
|
| Send email to the article author |
|
|
|
| Add your comments about this article |
|
|
|
